The safeguard, a £40m marking from Chelsea, captained his nation amid their 7-1 semi-last thrashing by Germany.
Luiz, 27, said: "If the World Cup had completed at the quarter-last stage then you wouldn't be making inquiries about my capacity.
"I've had room schedule-wise to process the end of our World Cup and now I'm prepared to do everything to help PSG."
The world's most extravagant safeguard, who can additionally play in midfield, held his first news meeting for the French champions since his turn, which happened amid the World Cup.
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Brazil's David Luiz scores a splendid free-kick against Colombia
Brazil's David Luiz scores splendid free-kick
"I feel advantaged. I'm a piece of a fabulous group in which everybody has something to show me. It's magnificent to be some piece of this undertaking," he said, while including that "Chelsea are history".
"I would like to be 100% one week from now and on the pitch as quickly as time permits. I'm prepared to help in any position on the field."
Luiz joined the Blues from Benfica for £21.3m in January 2011 and showed up for the club.
He was a piece of the Chelsea side that beat Bayern Munich in the 2012 Champions League last.
PSG president Nasser Al-Khelaifi said: "David Luiz will help us accomplish our objective of winning the Champions League."
He likewise said that the club won't be marking Real Madrid and Argentina winger Angel Di Maria.
"The reality of the matter is that we have held chat with Real Madrid president Florentino Perez yet he is excessively lavish for us. We have halted arrangements," the Qatari include
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